Monday, 16 November 2015

JOURNEY THROUGH THE LIFE HISTORY OF DMITRI IVANOVICH MENDELEEV

DMITRI MENDELEEV (LIVED 1834 – 1907)

INTRODUCTION


Dmitri Mendeleev was passionate about chemistry.  His deepest wish is to find a better way of organizing the subject.
Mendeleev’s wish led to his discovery of the periodic law and his creation of the periodic table.  One of the most iconic symbol ever seen in science almost everyone recognizes it instantly.  Science has few other creations as well known as the periodic table using his periodic table.  Mendeleev predicted his existence and properties of new chemical elements when these elements were discovered, his place in the history of science was assured.


EARLY LIFE AND EDUCATION
Dmitri Ivanovich Mendeleev was born February 8, 1834 in Verchnie Armzyani, in the Russian province by Siberia.   His family was unusually large.  He may have had as many as 16 brothers and sisters, although the exact numbers is uncertain.
When his father was a teacher who had graduated at Saint Petersburg’s main pedagogic institute a teacher training institution.
When h is father went bling, his mother reopened a glass factory which had originally been started by his father and then closed.  His father died when Mendeleev was just 13 and the glass factory burned down when he was 15.
Aged 16, he moved to Saint Petersburg, which as the Russia’s capital city.  He won a place at his father’s old college in part because the head of the college had known his father.  There, Mendeleev trained to be a teacher.
In 1855, aged 21 he got a job teaching science in Sismeropol, Crimea, but soon returned to St. Petersburg.  There he studied for a master’s degree in chemistry at the University at St. Petersburg.  He was awarded his degree in 1856.
THE PERIODIC TABLE
Mendeleev was certain that better more fun, damental principles could be found, this was his mind set when in 1869.  He began writing a second volume of his book.  The principle of chemistry at the heart of chemistry were its elements what wondered Mendeleev could they reveal to him if he could find someway of organizing them logically.  He wrote the names of the 65 known elements on cards, much like playing card one element on each card.  He then wrote the fundamental properties of every element on its own card including atomic weight.  He saw that atomic weight was important in some way.  The behavior of elements seemed to repeat as their atomic weights increased but he could not see the pattern.
Convinced that he was a close to discovering something significant, Mendeleev moved the cards about four hour after hour until finally he fell asleep at his desk.
When he awake, he found that this subconscious mind had done his work for him.  He now knew the pattern the elements followed, he later wrote.
Why was Mendeleev’s periodic table successful?
As with many discoveries in science, there is a time when a concept becomes ripe for discovery and this was the case with the periodic table in 1869.
Later Meyer, for example, had proposed a rough periodic table in 1864 and by 1868 had devised one that was very similar to Mendeleev’s but he did not publish it until 1870.
John Newlands published a periodic table in 1865.  Newlands wrote his own law of periodic behavior.  Newlands also predicted the existence of a new element (Germanium) based on a gap in his table.  Unfortunately for Newlands, his work was largely ingnored.
The reason Mendeleev became the leader as the pack was probably because he not only showed how the elements could be organized, but he used his periodic table to propose that some of the elements, whose behaviors did not agree with his predictions, must have had their atomic weights measured incorrectly.
Predict the existence of eight new elements Mendeleev even predicted the properties these elements would have.  It turned out that chemists had measured some atomic weights incorrectly.  Mendeleev was right now scientists everywhere sat up and paid attention to his periodic table as new elements that he had predicted were discovered.  Mendeleev’s fane and scientific reputation were enhanced further.  In 1905, the British Royal Society gave him its highest honor, the coopleymedal and in the same year he was elected to the Royal Swedish Academy of Sciences.
Element 101 is named Mendeleevicem in his honor.
TECHNICAL ACTIVITIES
Mendeleev also showed a great interest in technology.  In 1863 he was immersed in the problems as the Baku Petroleum industry.  He suggested a pipeline should be build to carry the oil from Baku to the Black Sea.  He noted that the system of leasing oil-rich government owned lands for a 4-year period tended to prevent large scale investment in needed equipment to modernize operations and he taught the government tax on petroleum products.  In 1876, Mendeleev visited the Pennsylvania oil field, brought back some technical ideas and presented an unflattering  views of America in his book.  The oil industry in the North American sate of Pennsylvania and the Caucasus.  He developed a theory that petroleum originated from the action of water on metallic carbides inside the earth.
PYROCOLLODION


Is a smokeless power invented by Dmitri Mendeleev.  Mendeleev discovered it in 1892 and proposed to use it to replace gun power in the Russian Navy.  This after was rejected because of cost and efficiency.  Pyrocollodion is known to be spontaneously combustible and explosive, when ignited.  It will burnt/explode quickly and with excessive heat output.  If ignited a tight contained space.  It will leave little to no remains such unburned power, particular kinds of flame scarring or smoke of any kind.  Pyrocollodion is a variant of nitro cellulose.  The natural ingredients found in Pyrocolloidon can now be used in the production of cocaine and cigarettes.
PYCNOMETER


A gas pycnometer is a laboratory device used for measuring the density or more accurately the volume of solids, be they regularly shaped, porous, or non-porous monolithic, powdered, granular or in some way comminuted, employing some method of gas displacement and the volume pressure relationship known as Boyle’s law.  A gas pycnometer is also sometimes referred to as a Helium pyconometer.
CONCLUSION


Born in Siberia, the last by at least 14 children.  Dmitri Mendeleev revolutionized our understanding as the properties of atoms and created a table that probably adorns every chemistry classroom in the world.  After his father went blind and could no longer support of the family, Mendeleev’s mother started a glass factory to help make ends meet.  But just as Mendeleev was finish high school, his father died and the glass factory burned down with most of her other children now out on their own.  His mother took her son to St. Petersburg, working tastelessly and successfully to get him into college.  In the late 1860’s, Mendeleev began working on his great achievement, periodic table of elements.
REFERENCES
·        Mendeleev’s collection – St. Petersburg
·        Masanori Kaji Mendeleev’s discovery of the periodic law.  The origin and the reception.


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